Copper benzoate is the chemical compound with the formula [Cu(C6H5CO2)2. This coordination complex derived from the cupric ion and the conjugate base of benzoic acid. Because copper emits blue when heated in a flame, this salt has found some use as a source of blue light in fireworks.[1]
Preparation is easily done by mixing aqueous solutions of sodium benzoate or potassium benzoate and copper sulfate. Solid copper benzoate forms as a bluish-green precipitate and can be collected by filtration. The equations for these reactions are:
2 CuSO4 + 4 KC6H5CO2 → Cu2(C6H5CO2)4 + 2 K2SO4
As for copper(II) acetate,[2] the benzoate adopts a Chinese lantern structure," wherein a pair of copper centers are linked by four bridging carboxylate ligands. Typically one site on each copper center is occupied by water, which can be replaced by other ligands.