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Iodate

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An Iodate is a salt of iodic acid. In the iodate anion, iodine is bonded to three oxygen atoms and the molecular formula is IO3. The molecular geometry of iodate is trigonal pyramid.

Iodate can be obtained by reducing periodate with a thioether. The biproduct of the reaction is a sulfoxide.

Iodates are a class of chemical compounds containing this group. Examples are sodium iodate (NaIO3), silver iodate (AgIO3), and calcium iodate (Ca(IO3)2). Iodates resemble chlorates with chlorine instead of iodine.

In acid conditions, iodic acid is formed. Potassium hydrogen iodate (KH(IO3)2) is a double salt of potassium iodate and iodic acid and an acid as well. Iodates are used in the iodine clock reaction

Potassium Iodate
Potassium iodate (KIO3) is a chemical compound. It is sometimes used in radiation treatment, as it can replace radioactive iodine from the thyroid. See potassium iodide for more information on this use.

Like potassium bromate, potassium iodate is occasionally used as a maturing agent in baking.

Potassium iodate is an oxidizing agent and as such it can cause fires if in contact with combustible materials or reducing agents. It can be prepared by reacting a potassium-containing base such as potassium hydroxide with iodic acid, for example:

HIO3 + KOH → KIO3 + H2O

It can also be prepared by adding iodine to a hot, concentrated solution of potassium hydroxide.

3 I2 + 6 KOH → KIO3<.sub> + 5 KI + 3 H2O

Sodium Iodate
Sodium iodate (NaIO3) is a chemical compound. Sodium iodate is an oxidizing agent and as such it can cause fires if in contact with combustible materials or reducing agents. It can be prepared by reacting a sodium-containing base such as sodium hydroxide with iodic acid, for example:

HIO3 + NaOH → NaIO3 + H2O

It can also be prepared by adding iodine to a hot, concentrated solution of sodium hydroxide.

3 I2 + 6 NaOH → NaIO3 + 5 NaI + 3 H2O

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